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It is believed that the mechanisms for the extremely high susceptibility of myeloid stem cells to the leukemogenic effects of etoposide is due to etoposide phenoxyl radicals (etoposide-O · ) formed from etoposide by myeloperoxidase.74,75 Etoposide-O · is reduced back to etoposide via oxidation of intracellular thiols (RSH), i.e., glutathione and sulfhydryl groups of proteins