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Structural characterization of glutamate isotopologues To gain structural insights into glutamate isotopologues, ddMS2 acquisition targeting each isotopologue was acquired using ion-paired LCMS on an Orbitrap Exploris 240 as described above

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Yet as our understanding of cellular signaling and regulatory pathways has developed, so has our insight into the involvement of GSH homeostasis in many other key processes, including the regulation of cellular proliferation and apoptosis and the post-transcriptional modification of proteins through S-glutathionylation, as well as the importance of GSH in the detoxification of hydroperoxides and diverse xenobiotic compounds