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In a recent review, Stampfli and Seebeck combined computational studies and experimental work to develop a Mth EgtB proposal, suggesting that protonation of Fe III -superoxo (9) by Tyr377 induces a thiyl radical of γ-GC, and deprotonation of the TMH imidazole ring initiates its attack to the electron-deficient thiyl radical (10)

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doi: 10.1016/j.redox.2016.08.015