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While both can appear on the chin and lower face, perioral dermatitis clusters in a tight perioral pattern rather than distributing diffusely across oily zones

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Orthogonal validation of NMR fragment hit 27 Encouraged by the relatively high binding affinity of compound 27 compared to expectations for fragments, we synthesised a series of analogues to explore the effect of modifying both the sulfonic acid and the ethoxy substituents on binding affinity (Table 1)